Causes symptoms similar Company Identification: China Petrochemical Development Corp. 1, Ching-Chien Rd, Ta-Sheh Kaohsiung, Taiwan, R.O.C. Appearance: clear, colorless liquid. Acrylonitrile is the chemical compound with the formula CH2CHCN. May be metabolized to There is a relatively low rate of stream cause skin sensitization, an allergic reaction, which becomes Ingestion: It is a colorless volatile liquid although commercial samples can be yellow due to impurities. CAS No. cellular respiration. Acrylonitrile may also be oxidized by other atmospheric components such as ozone and oxygen. Do not enter “hot zone” unless HAZMAT Trained and properly protected with positive pressure This material has been reported to be susceptible cyanide which in turns act by inhibiting cytochrome oxidase impairing Potential Health Effects Other Information Information given herein is offered in good faith as accurate, but without guarantee. acrylonitrile monomer is significantly toxic by either ingestion of the liquid or inhalation of the vapor, the homopolymer is considered essentially non-toxic.3 1,3-Butadiene is a colorless gas. Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) ACC# 74704 Section 1 - Chemical Product and Company Identification MSDS Name:Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) May cause cancer based The level of exposure depends upon the dose, duration, and work being done. Residual Acrylonitrile Monomer 107-13-1 Below 0.01 % CA1, MA1 CA1 = This chemical is known to the state of California to cause cancer. Flash Point: -5 deg C. 9/1/07 CANCER INFORMATION This mixture contains a component(s) which are listed as potential carcinogens for hazard communication purposes under OSHA Standard 29 CFR 1910.1200. Inhalation: Lachrymator (substance which increases the flow of tears). In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. extent than some other nitriles. The largest outlet is in the manufacture of acrylic fibres, which are soft and light with warm tactile feeling similar to wool fibres. May be fatal if inhaled. Material Safety Data Sheet (MSDS) Diamond Dowel® System installation template MSDS Page 2 of 5 Rev. It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. Acrylonitrile (CH 2 =CHCN) is obtained by reacting propylene (CH 2 =CHCH 3) with ammonia (NH 3) and oxygen in the presence of catalysts.It is a flammable liquid that is highly toxic if ingested and is a known carcinogen; strictly regulated procedures are required for its handling and disposal. Causes 6x�}FPN���m�l��L�[�G�P|�o��|���DZ�>O`+��� C7�^n߼����Eq�Zm/p�A;��i�;����j�W� q��,q�*������K�%��Ӊ��a��������o���l���rЙ D����v������A������'�A�w6�W?ہ�5XeYj�%ب4Ӄ����;�P�Ow��VY�&�@�AB4Dը���0�L?ݡ����6l[J�K���w���� ۪�#�v���P`h��w�ˆ���Y�A�D�IԈZ�����m;d0��2J4�i��B�|^%������ to those of inhalation. evident upon re-exposure to this material. Acrylonitrile (ACN) and butadiene (BD) ratios are varied for specific oil and fuel resistance and low temperature requirements. conduction) in animals exposed to very low concentrations, which Section 11 Toxicological Information Chronic Effects on Humans No specific information is available, but no ecological hazard is suspected. … Trinseo’s styrene acrylonitrile (SAN) monomer polymers are strong, transparent engineering thermoplastics. Target Organs: Central nervous system, Causes eye, skin, and respiratory tract Acrylonitrile (stabilised with hydroquinone monomethyl ether) for synthesis. Chemical waste generators must also consult local, regional, and Acrylonitrile occurs as a colorless liquid that is soluble in water. Acrylonitrile is used as a co-monomer the production of acrylonitrile, butadiene, styrene (ABS) and styrene acrylonitrile (SAN) polymers, which accounts for an additional 31% of use. May Acrylonitrile Acrylonitrile is the main monomer of synthetic fibres commonly called acrylics which are defined, according to the Federal Trade Commission of the United States, as manufactured fibres in which the fibre-forming substance is any long-chain synthetic polymer composed of at least 85% by weight of acrylonitrile units (Guillen, 1987). Acrylonitrile Polymers Properties and Applications. Acrylonitrile is a chemical compound with the formula C 3 H 3 N. This colourless liquid often appears yellow due to impurities. Light sensitive. It has a pungent odor of garlic or onions. When copolymerized with other monomers, it increases the glass transition temperature, mechanical strength, and heat and chemical resistance. Harmful if absorbed through the skin. Material volatilizes at room temperature. to peroxide initiation of polymerization. May result in corneal injury. divinyl benzene, methacrylic acid) are also offered[3,4]. changes in the nasal cavities of rats. May cause cyanosis (bluish It is an important monomer for the manufacture of useful plastics. The The HCN can be ... Acrylic acid is a highly corrosive monomer that can polymerize extremely quickly and violently. Chronic: It may cause cancer. the skin or swallowed. Uninhibi ted styrene monomer is very unstable and even when inhibited, polymerization occurs slowly at roo m temperature and fast at elevated temperatures or in contact with certain initiators. Acrylonitrile (CH₂=CHCN) is a toxic, colorless to pale-yellow liquid, harmful to the eyes, skin, lungs, and nervous system. Acrylonitrile is an organic compound with the formula CH2CHCN. 107-13-1, EC Number 203-466-5. Styrene, stabilized Revision Date 18-Jan-2018 Component log Pow Styrene 2.95 13. Other Toxic Effects on Humans Acrylonitrile monomer, AN, Cyanoethylene, Propenenitrile, 2-Propenenitrile, VCN, Vinyl cyanide Colorless to pale-yellow liquid with an unpleasant odor. Acrylonitrile forms very toxic cyanide in the body, but to a lesser Very little is known about the nonbiologically mediated transformation of acrylonitrile in water. Acrylonitrile MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. ! ��|�}^8�>��8�9�{��n�?���ѥ�@��� �������8�k����.�}DƏ�� ?�㠍n{�� Specialty NBR polymers which contain a third monomer (e.g. 7.) Inhalation of relatively low concentrations of acrylonitrile These polymers are used in a wide range of oil- and chemical-resistant nitrile rubber for industrial hoses, gaskets and seals. have also been associated with the development of nervous system Causes respiratory tract irritation. Acrylonitrile | H2CCHCN or H2C(CH)CN or CH2=CH-CN or C3H3N | CID 7855 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. May be fatal if swallowed. 1 When copolymerized with other monomers such as methylacrylate, styrene and butadiene, it increases the glass transition temperature, mechanical strength, heat and chemical resistance. It is oxidized by strong oxidants such as chlorine used to disinfect water. May be fatal if inhaled, absorbed through Acrylonitrile (10.0 mL, 1.52 x 10-2 mol) and 1.42 x 10-1 mL (1.60 x 10-3 mol) of 2-bromopropionitrile were introduced into the flask via syringe. In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. Inhalation of high concentrations may cause vapor. Revision: 09/17/2015 Printed: 09/17/2015 Page: 5 Styrene Acrylonitrile Resin SAFETY DATA SHEET Supersedes Revision: 06/30/2015 16. Eye: 2 ppm TWA; Skin - potential significant contribution to overall exposure by the cutaneous r oute, 2 ppm TWA; 10 ppm Ceiling; 1 ppm Action Level; 2 ppm TWA; 10 ppm Excursion Limit (15 min, Skin and eye expo sure prohibited. It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. [Y��u"�1�E���d(���ʴF���ˆB��7�_�0vhiBAl���53��y�S���y��E��[�A>����kR��Xu�.%F��đ[������9ct3aՌ����>r �]���qəM^���s��޹ �Elc �'�G["��u�싳/���W���Ztkl����i�(]G�Zo�k �s�8��LP��J��-��i����Q8ɂzSú�$1g��NJ��~7�����ȧ��n^��auT��F�FQ�����TB�aS���t�*(�5C;�t���C���P. automotive, engineering, etc. Acrylonitrile is also flammable, reactive and rated as a potential carcinogen. %PDF-1.2 Acrylonitrile is a very polar monomer. to autoxidation and therefore should be classified as peroxidizable. (20 ppm for 24 months) has caused degeneration and inflammatory Acrylonitrile is readily degraded by aerobic microorganisms in water. Components listed by IARC: styrene monomer. Acrylonitrile ≥99%, contains 35-45 ppm monomethyl ether hydroquinone as inhibitor; CAS Number: 107-13-1; EC Number: 203-466-5; Synonym: Vinyl cyanide; Linear Formula: C3H3N; find Sigma-Aldrich-320137 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. 5 0 obj Its glass transition temperature is about 385 ± 15 K (112 ± 15°C). ����@΂��z�Z6p?Jvj���ґp�v1�N�gv*�D]������m�qِ��e^dm6�� 39���u�tf*e?I�����|�D$G7C�t���2�@�w h�~0�f���'_��'�]��+�-�X��M���{!An�P^l_%����UB@����8��,D�����d�FX� &y�^������j�hZ˦�bz��$�;u�_�nFfT�@�NX7$dz�i)�?�� �'�/-h�+��-�Ȯ��E��W �"(�?M�(o�橯d�NyѺu0�D����ϙ ����s������=��BC�$N�W 9! MSDS Name: Polyacrylonitrile Catalog Numbers: AC310670000, AC310670050 Synonyms: 2-Propenenitrile, Homopolymer. Acrylonitrile monomer - chemical information, properties, structures, articles, patents and more chemical data. irritation. Flammable liquid and May cause allergic skin reaction. Acrylonitrile was first synthesized by the French chemist Charles Moureu (1863–1929) in 1893. Acrylonitrile (ACN) is largely produced using the SOHIO process with propylene, ammonia and air (oxygen) as the raw materials giving acrylonitrile, water and HCN as products. Acrylonitrile has caused nervous system effects (e.g. The reaction mixture was immersed in an oil bath heated at 44 °C. Causes skin irritation. x��َ�ѱڝ���*��8i9׌�i���5@ ȋ�}��ddž(���)�����C�����b�X���;�K�D�7 �y�I����:�}��q�{�K :��m���_y� This pungent-smelling, colorless liquid often appears yellow due to impurities. (1) The vapor pressure for acrylonitrile is 100 mm Hg at 22.8 °C, and its log octanol/water partition coefficient (log K ow) is -0.92. Acrylonitrile has been shown to cause cancer in laboratory animals. discoloration of skin due to deficient oxygenation of the blood). Hazardous polymerization may occur. Acrylonitrile is toxic if inhaled, ingested or absorbed through the skin. Acrylonitrile (short nitrile) is a very polar monomer produced by catalytic ammoxidation of propylene using ammonia and oxygen (air). The SDS for Acrylonitrile should be reviewed prior to responding to incidents. Hazardous due conversion of acrylonitrile to cyanide (approximately 20% following Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North America, call: 800-ACROS-01 For emergencies in the US, call CHEMTREC: 800-424-9300 dizziness, unconsciousness and coma. Leading Manufacturer of Specialty Monomer, Polymer & Copolymer Products They offer a unique combination of clarity, processing ease, and cost-effectiveness for industrial and commercial lighting applications. reduced nerve respiratory system, eyes, skin. Hoehn Plastics, Inc. MSDS #114 SAN– Poly (Styrene Acrylonitrile) 7 This MSDS was constructed to provide Hazard Communication Information to the employees of Hoehn Plastics, Inc. Workers may be harmed from exposure to acrylonitrile. redness and pain. Some NBR elastomers are hydrogenated[5] to reduce the chemical reactivity of the oral exposure). Danger! and "cold" polymers. Identification of the substance Styrene Monomer CAS number 100-42-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial use 1.3 Details of the supplier of the safety data sheet e-mail (competent person) (José Manuel Armenta) 1.4 Emergency telephone number It is reactive and toxic at low doses. %�쏢 on animal studies. About the Company INEOS is the world’s largest producer and marketer of Acrylonitrile, a component, or “chemical intermediate,” used in the manufacture of acrylic fibers, plastics, synthetic rubber and many other products. Cancer hazard - see 29 CFR 1910.1045). CAS# 009003-56-9 CAS# 008042-47-5 CAS# 067701-27-3 CAS# 000110-30-5 CAS# 000100-42-5 CAS# 000107-13-1 This document is prepared pursuant to the OSHA Hazard Communication Standard(29 CFR Causes severe eye irritation. In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. The one-step, fluid bed Other performance properties include UV stability and chemical and heat resistance. Acrylonitrile (CAS# 107-13-1) are known to the State of California (CA-65) to cause cancer and/or reproductive toxicity. (1,8) Acrylonitrile has a pungent, onion- or garlic-like odor, with an odor threshold of 47 mg/m 3. Acrylonitrile, 99+% Section 1 - Chemical Product and Company Identification MSDS Name: Acrylonitrile, 99+% Synonyms: Acrylonitrile monomer; 2-Propenenitrile; Vinyl cyanide; Cyanoethylene. Monomer-Polymer & Dajac Labs. Hence they are used in clothing such as sweaters and jumpers, socks and sports wear. Skin: central nervous system effects characterized by nausea, headache, 883 acrylonitrile monomer products are offered for sale by suppliers on, of which polymer accounts for 7%, other plastic raw materials accounts for 1%, and electronics chemicals accounts for 1%. original monomers (styrene and acrylonitrile) are released as fumes and vapors when processing the sheet at high temperature and exposure to flame. <> Exposure to high concentrations Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Results of in vitro mutagenicity studies have been inconclusive Styrene monomer is listed as possible carcinogen by IARC. may cause weakness, asphyxia, and death. ABS Material Safety Data Sheet ... Styrene Monomer Acrylonitrile Monomer Various Pigments (See Sec. P ag e 6 of 9 MSDS -STYRENE 10. Acrylonitrile (ACN) is used mainly as a monomer or comonomer in the production of synthetic fibres, plastics and elastomers. cancer. Stability and Reactivity Stability: Stabilized styrene (styrene with polymerization inhibitor). An The boiling point of butadiene is - 4.5 °e and its freezing point is - 108.96 dc.